Volume collapse transition in Ce
Crystalline Ce has a remarkable phase diagram in that is the solid state analogue of a Van der Walls system with a line of discontinuous transitions ending at a critical point.
The two phases alpha and gamma have the same cubic symmetry and differ only on density just like water and vapor but in the solid state!.
However unlike water and vapor the critical exponents close to the critical point are not three dimensional Ising critical exponents, as one would naively guess from symmetries, but classical (Gaussian) exponents.… Read the rest