Ionic liquids: a spectroscopic investigation

Ionic liquids (IL) are salts formed by organic cations, like imidazolium, pyrrolidinium, ammonium or alkyl phosphonium, and organic/inorganic anions, like hexafluorophosphate, tetrafluoroborate, triflate, dicyanamide, tetracyanamethanide or bis(trifluoromethanesulfonyl)imide (TFSI). The presence of such bulky and asymmetric ions decreases the ion-ion interactions and lowers the melting point with respect to more classical salts, reaching values as low as -20°C.

ILs posses many peculiar properties, such as an extremely low vapor pressure, a high ionic conductivity, a high thermal, chemical and electrochemical stability, a high thermal capacity and a good solvent capability.… Read the rest

Solid state hydrogen storage

Hydrogen is attracting renewed interest as an energy carrier, due to the necessity of finding ecological energy media which may decrease the environmental pollution from fossil fuels. Hydrogen storage represents a nodal point for the development of a hydrogen economy.

Of the three possible ways to store hydrogen, i.e. as high pressure gas, as a liquid (~20 K at atmospheric pressure), or as hydrides in solids, the latter one appears as the most promising, due to the high mass and volume density and safety.… Read the rest